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Issue 6, 2018
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Teaching an old molecule new tricks: evidence and rationalisation of the slow magnetisation dynamics in [DyTp2Acac]

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Abstract

We report the luminescence and magnetic properties of the mononuclear Dy(III) complex [DyTp2Acac] (Tp = tris-pyrazolylborohydride and Acac = 2,4-pentanedionate). This complex displays peculiar slow magnetisation dynamics at low temperature in the absence of a static field, which we managed to interpret using its resolved luminescence spectrum and ab initio calculations.

Graphical abstract: Teaching an old molecule new tricks: evidence and rationalisation of the slow magnetisation dynamics in [DyTp2Acac]

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Publication details

The article was received on 25 Feb 2018, accepted on 03 Apr 2018 and first published on 04 Apr 2018


Article type: Research Article
DOI: 10.1039/C8QI00174J
Citation: Inorg. Chem. Front., 2018,5, 1346-1353
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    Teaching an old molecule new tricks: evidence and rationalisation of the slow magnetisation dynamics in [DyTp2Acac]

    F. Guégan, F. Riobé, O. Maury, J. Jung, B. Le Guennic, C. Morell and D. Luneau, Inorg. Chem. Front., 2018, 5, 1346
    DOI: 10.1039/C8QI00174J

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