Jump to main content
Jump to site search

Issue 5, 2018
Previous Article Next Article

Highly stable Y(III)-based metal organic framework with two molecular building block for selective adsorption of C2H2 and CO2 over CH4

Author affiliations

Abstract

We successfully designed and constructed a novel mircroporous metal organic framework [Y4(TATB)2]·(DMF)3.5·(H2O) (ZJU-16, H3TATB = 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tribenzoic acid) from two different types of MBBs (molecular building block) [Y33-OH)(COO)6] and [Y93-OH)14(COO)12] and a tricarboxylic acid organic linker via solvothermal reaction. ZJU-16 exhibited high thermal and chemical stability; it is stable up to 500 °C and also maintains its integrity in neutral (water), basic and acidic aqueous solutions. Due to suitable pore size and high stability, the desolvated ZJU-16a demonstrates moderately high selective separation of C2H2/CH4 and CO2/CH4 at room temperature.

Graphical abstract: Highly stable Y(iii)-based metal organic framework with two molecular building block for selective adsorption of C2H2 and CO2 over CH4

Back to tab navigation

Supplementary files

Publication details

The article was received on 31 Jan 2018, accepted on 26 Mar 2018 and first published on 26 Mar 2018


Article type: Research Article
DOI: 10.1039/C8QI00083B
Citation: Inorg. Chem. Front., 2018,5, 1193-1198
  •   Request permissions

    Highly stable Y(III)-based metal organic framework with two molecular building block for selective adsorption of C2H2 and CO2 over CH4

    X. Duan, R. Lv, Z. Ji, B. Li, Y. Cui, Y. Yang and G. Qian, Inorg. Chem. Front., 2018, 5, 1193
    DOI: 10.1039/C8QI00083B

Search articles by author

Spotlight

Advertisements