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Two isomorphous azide/formate Mn(II) coordination polymers show spin-canted antiferromagnetism only in the formate system

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Abstract

Two isostructural 3D complexes [Mn(L)(N3)·MeOH]n (1) and [Mn(L)(HCO2)·MeOH]n (2) (HL = pyrazine-2-carboxylic acid) were synthesized by using a solvothermal method. Magnetic studies indicate that 1 was a strong antiferromagnet, whereas 2 was a weak antiferromagnet with TN 38.5 K.

Graphical abstract: Two isomorphous azide/formate Mn(ii) coordination polymers show spin-canted antiferromagnetism only in the formate system

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Publication details

The article was received on 13 Dec 2017, accepted on 19 Jan 2018 and first published on 19 Jan 2018


Article type: Research Article
DOI: 10.1039/C7QI00789B
Citation: Inorg. Chem. Front., 2018, Advance Article
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    Two isomorphous azide/formate Mn(II) coordination polymers show spin-canted antiferromagnetism only in the formate system

    J. Wang, Q. Yang, Y. Zhang, G. Che, J. Zhao and F. Liu, Inorg. Chem. Front., 2018, Advance Article , DOI: 10.1039/C7QI00789B

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