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The influence of an external magnetic field and magnetic-site dilution on the magnetization dynamics of a coordination network based on ferromagnetic coupled dinuclear dysprosium(III) units

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Abstract

We report the synthesis and magnetic properties of a μ2-OH bridged dinuclear Dy(III) single-molecule magnet (SMM), [Dy2(apca)42-OH)2(H2O)2]n (Dy, Hapca = 3-aminopyrazine-2-carboxylic acid), which was assembled in a two-dimensional (2D) network. Magnetic studies reveal that Dy exhibits ferromagnetic interactions, multi-process slow relaxation of magnetization and hysteresis loops. The influence of an external magnetic field and magnetic-site dilution on the magnetic properties was also studied.

Graphical abstract: The influence of an external magnetic field and magnetic-site dilution on the magnetization dynamics of a coordination network based on ferromagnetic coupled dinuclear dysprosium(iii) units

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Publication details

The article was received on 25 Oct 2017, accepted on 06 Dec 2017 and first published on 06 Dec 2017


Article type: Research Article
DOI: 10.1039/C7QI00663B
Citation: Inorg. Chem. Front., 2018, Advance Article
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    The influence of an external magnetic field and magnetic-site dilution on the magnetization dynamics of a coordination network based on ferromagnetic coupled dinuclear dysprosium(III) units

    X. Zhang, N. Xu, W. Shi, B. Wang and P. Cheng, Inorg. Chem. Front., 2018, Advance Article , DOI: 10.1039/C7QI00663B

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