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Polymerization Based on Alternating Insertion of Isocyanide and Alkyne into Palladium–Carbon Bond

Abstract

The first polymerization system to be based on the alternating insertion of isocyanide and alkyne into palladium–carbon bonds has been developed. Aryl isocyanide containing isocyanide and alkyne moieties in a single molecule was polymerized using chloro(methyl)bis(triphenylphosphine)palladium as a catalyst. The resulting polymer was characterized by IR and NMR spectroscopic analysis, which showed that the polymerization reaction proceeded through the intramolecular alternating insertion of isocyanide and alkyne to produce indole units in the main chain.

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Publication details

The article was received on 07 Mar 2018, accepted on 16 Apr 2018 and first published on 17 Apr 2018


Article type: Paper
DOI: 10.1039/C8PY00381E
Citation: Polym. Chem., 2018, Accepted Manuscript
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    Polymerization Based on Alternating Insertion of Isocyanide and Alkyne into Palladium–Carbon Bond

    Y. Kataoka, N. Kanbayashi, T. Okamura and K. Onitsuka, Polym. Chem., 2018, Accepted Manuscript , DOI: 10.1039/C8PY00381E

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