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Highly reactive α-bromoacrylate monomers and Michael acceptors obtained by Cu(II)Br2-dibromination of acrylates and instantaneous E2 by a ligand

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Abstract

Depending on the order of their addition to the reaction mixture, acrylates can undergo SET-LRP or dibromination by Cu(II)Br2 and spontaneously dehydrohalogenate to provide the corresponding highly reactive α-bromoacrylate monomer and Michael acceptor.

Graphical abstract: Highly reactive α-bromoacrylate monomers and Michael acceptors obtained by Cu(ii)Br2-dibromination of acrylates and instantaneous E2 by a ligand

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Publication details

The article was received on 27 Jan 2018, accepted on 16 Mar 2018 and first published on 20 Mar 2018


Article type: Communication
DOI: 10.1039/C8PY00155C
Citation: Polym. Chem., 2018, Advance Article
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    Highly reactive α-bromoacrylate monomers and Michael acceptors obtained by Cu(II)Br2-dibromination of acrylates and instantaneous E2 by a ligand

    A. Moreno, J. Lejnieks, L. Ding, S. Grama, M. Galià, G. Lligadas and V. Percec, Polym. Chem., 2018, Advance Article , DOI: 10.1039/C8PY00155C

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