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Scope and limitations of ring-opening copolymerization of trimethylene carbonate with substituted γ-thiolactones

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Abstract

Functional (co)polymers are increasingly developed by ring-opening polymerization of functional cyclic esters and cyclic carbonates for a wide range of applications. Following this trend and aiming to challenge the polymerization of substituted γ-thiolactones, we studied the ring-opening copolymerization of recently developed γ-thiolactones with trimethylene carbonate in order to prepare new poly(carbonate-co-thioester)s with phosphonated or fluorinated pendant groups.

Graphical abstract: Scope and limitations of ring-opening copolymerization of trimethylene carbonate with substituted γ-thiolactones

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Publication details

The article was received on 23 Jan 2018, accepted on 06 Apr 2018 and first published on 09 Apr 2018


Article type: Paper
DOI: 10.1039/C8PY00127H
Citation: Polym. Chem., 2018, Advance Article
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    Scope and limitations of ring-opening copolymerization of trimethylene carbonate with substituted γ-thiolactones

    M. Langlais, O. Coutelier, S. Moins, J. De Winter, O. Coulembier and M. Destarac, Polym. Chem., 2018, Advance Article , DOI: 10.1039/C8PY00127H

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