Jump to main content
Jump to site search

Issue 11, 2018
Previous Article Next Article

Triaryl-1,4-diamine-based polysquaraines: effect of co-solvent and monomer insertion on optoelectronic properties

Author affiliations

Abstract

A series of N1,N4-didodecyl-N1,N4-diphenylbenzene-1,4-diamine-based polysquaraines have been synthesized under microwave irradiation in the absence of any catalyst. The effect of the solvent of polymerization, on the squaric acid catenation (1,2 and 1,3 linkages), has been studied and polysquaraines integrating linear chains in their backbone have been advantageously obtained by using di-functional alcohol during the polymerization. Such obtained polymers exhibit a broad emission with a quantum yield up to 18%. The latter were then tested in OLED devices exhibiting a promising white emission.

Graphical abstract: Triaryl-1,4-diamine-based polysquaraines: effect of co-solvent and monomer insertion on optoelectronic properties

Back to tab navigation

Supplementary files

Publication details

The article was received on 08 Dec 2017, accepted on 24 Jan 2018 and first published on 24 Jan 2018


Article type: Communication
DOI: 10.1039/C7PY02056B
Citation: Polym. Chem., 2018,9, 1288-1292
  •   Request permissions

    Triaryl-1,4-diamine-based polysquaraines: effect of co-solvent and monomer insertion on optoelectronic properties

    G. Garbay, T. Tailliez, E. Pavlopoulou, J. Oriou, M. Bezirdjoglou, G. Hadziioannou, E. Cloutet and C. Brochon, Polym. Chem., 2018, 9, 1288
    DOI: 10.1039/C7PY02056B

Search articles by author

Spotlight

Advertisements