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Issue 20, 2018
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Iridium-catalyzed C–H phosphoramidation of N-aryl-7-azaindoles with phosphoryl azides

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Abstract

An iridium-catalyzed C–H phosphoramidation of N-aryl-7-azaindoles with phosphoryl azides was developed, affording a series of 7-azaindole phenylphosphoramidates in moderate to good yields. This protocol displays good functional group tolerance, which offers a novel and direct approach to access 7-azaindole phenylphosphoramidates.

Graphical abstract: Iridium-catalyzed C–H phosphoramidation of N-aryl-7-azaindoles with phosphoryl azides

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Publication details

The article was received on 02 Apr 2018, accepted on 27 Apr 2018 and first published on 27 Apr 2018


Article type: Communication
DOI: 10.1039/C8OB00776D
Citation: Org. Biomol. Chem., 2018,16, 3711-3715
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    Iridium-catalyzed C–H phosphoramidation of N-aryl-7-azaindoles with phosphoryl azides

    C. Pan, Y. Wang, C. Wu and J. Yu, Org. Biomol. Chem., 2018, 16, 3711
    DOI: 10.1039/C8OB00776D

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