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Gold(I)-catalyzed cross-coupling reactions of aryldiazonium salts with organostannanes

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Abstract

Gold(I)-catalyzed cross-coupling reactions of aryldiazonium salts with organostannanes are described. This redox neutral strategy offers an efficient approach to diverse biaryls, vinyl arenes and arylacetylenes. Monitoring the reaction with NMR and ESI-MS provided strong evidence for the in situ formation of Ph3PAuIR (R = aryl, vinyl and alkynyl) species which is crucial for the activation of aryldiazonium salts.

Graphical abstract: Gold(i)-catalyzed cross-coupling reactions of aryldiazonium salts with organostannanes

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Publication details

The article was received on 14 Mar 2018, accepted on 21 Mar 2018 and first published on 21 Mar 2018


Article type: Communication
DOI: 10.1039/C8OB00630J
Citation: Org. Biomol. Chem., 2018, Advance Article
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    Gold(I)-catalyzed cross-coupling reactions of aryldiazonium salts with organostannanes

    M. O. Akram, P. S. Shinde, C. C. Chintawar and N. T. Patil, Org. Biomol. Chem., 2018, Advance Article , DOI: 10.1039/C8OB00630J

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