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Issue 15, 2018
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Carbonylative coupling of N-chloroamines with alcohols: synthesis of esterification reagents

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Abstract

Herein we report a new method for the carbonylative synthesis of carbamates. Starting from N-chloroamines and alcohols, with copper or Pd/C as the catalyst, the corresponding carbamates were produced in moderate to good yields. No additional oxidant or base is needed in this system. Notably, the produced benzotriazole-carboxylates can be used as esterification reagents.

Graphical abstract: Carbonylative coupling of N-chloroamines with alcohols: synthesis of esterification reagents

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Publication details

The article was received on 22 Feb 2018, accepted on 26 Mar 2018 and first published on 26 Mar 2018


Article type: Communication
DOI: 10.1039/C8OB00462E
Citation: Org. Biomol. Chem., 2018,16, 2643-2646
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    Carbonylative coupling of N-chloroamines with alcohols: synthesis of esterification reagents

    Z. Yin, Z. Wang and X. Wu, Org. Biomol. Chem., 2018, 16, 2643
    DOI: 10.1039/C8OB00462E

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