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C(sp2)–H functionalization of aldehyde-derived hydrazones via a radical process

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Abstract

This review is focused on the recent advances in the C(sp2)–H functionalization of aldehyde-derived hydrazones via a radical process. Diverse substituted hydrazones including N-heterocycles are afforded under mild conditions with excellent selectivities. In general, an aminyl radical as the key intermediate is involved during the reaction process, and a broad reaction scope with good functional group tolerance can be observed. In some cases, a photocatalyst under visible light irradiation is involved, which initiates the radical reaction.

Graphical abstract: C(sp2)–H functionalization of aldehyde-derived hydrazones via a radical process

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Publication details

The article was received on 08 Jan 2018, accepted on 04 Feb 2018 and first published on 05 Feb 2018


Article type: Review Article
DOI: 10.1039/C8OB00056E
Citation: Org. Biomol. Chem., 2018, Advance Article
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    C(sp2)–H functionalization of aldehyde-derived hydrazones via a radical process

    X. Xu, J. Zhang, H. Xia and J. Wu, Org. Biomol. Chem., 2018, Advance Article , DOI: 10.1039/C8OB00056E

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