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Issue 15, 2018
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Bis(phenylsulfonyl)methane mediated synthesis of olefins via a halogen elimination and double bond migration

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Abstract

An effective dehydrochlorination of bis(phenylsulfonyl)alkane to prepare alkene building blocks is developed. The elimination together with double bond migration results in a variety of β,γ-unsaturated bis(phenylsulfonyl)olefins in good yields with only E geometry. The following chemical diversification represents an easy and straightforward access to a series of alkene building blocks.

Graphical abstract: Bis(phenylsulfonyl)methane mediated synthesis of olefins via a halogen elimination and double bond migration

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Publication details

The article was received on 05 Jan 2018, accepted on 13 Mar 2018 and first published on 14 Mar 2018


Article type: Communication
DOI: 10.1039/C8OB00033F
Citation: Org. Biomol. Chem., 2018,16, 2619-2622
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    Bis(phenylsulfonyl)methane mediated synthesis of olefins via a halogen elimination and double bond migration

    J. Jiang, Y. Hu, X. Cai, L. Wang, Y. Hu, S. Chen, S. Zhang and Y. Zhang, Org. Biomol. Chem., 2018, 16, 2619
    DOI: 10.1039/C8OB00033F

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