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Nucleophilic trifluoromethylthiolation of bromoalkynones with AgSCF3: C(sp)–SCF3 bond formation towards ynonyl trifluoromethyl sulfides

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Abstract

An AgSCF3 mediated nucleophilic trifluoromethylthiolation reaction for C(sp)–SCF3 bond formation is reported. This nucleophilic trifluoromethylthiolation reaction of bromoalkynones afforded various useful ynonyl trifluoromethyl sulfides in high yields. Interestingly, the over-addition of AgSCF3 is avoided in our approach.

Graphical abstract: Nucleophilic trifluoromethylthiolation of bromoalkynones with AgSCF3: C(sp)–SCF3 bond formation towards ynonyl trifluoromethyl sulfides

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Publication details

The article was received on 02 Jan 2018, accepted on 02 Feb 2018 and first published on 02 Feb 2018


Article type: Communication
DOI: 10.1039/C8OB00007G
Citation: Org. Biomol. Chem., 2018, Advance Article
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    Nucleophilic trifluoromethylthiolation of bromoalkynones with AgSCF3: C(sp)–SCF3 bond formation towards ynonyl trifluoromethyl sulfides

    H. Jiang, R. Zhu, C. Zhu, F. Chen and W. Wu, Org. Biomol. Chem., 2018, Advance Article , DOI: 10.1039/C8OB00007G

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