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Issue 7, 2018
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DBU-promoted carbonylative synthesis of 1,3-oxathiolan-2-ones from propargylic alcohols with TFBen as the CO source

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Abstract

A DBU-promoted carbonylative cyclization of propargylic alcohols with sulfur was developed. Various 1,3-oxathiolan-2-ones were produced in 61–98% yields under mild conditions in the absence of metal catalysts. TFBen (benzene-1,3,5-triyl triformate) as an efficient and solid CO surrogate and S8 as an ideal sulfur source were employed and incorporated.

Graphical abstract: DBU-promoted carbonylative synthesis of 1,3-oxathiolan-2-ones from propargylic alcohols with TFBen as the CO source

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Publication details

The article was received on 20 Dec 2017, accepted on 11 Jan 2018 and first published on 11 Jan 2018


Article type: Communication
DOI: 10.1039/C7OB03145A
Citation: Org. Biomol. Chem., 2018,16, 1065-1067
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    DBU-promoted carbonylative synthesis of 1,3-oxathiolan-2-ones from propargylic alcohols with TFBen as the CO source

    J. Ying, C. Zhou and X. Wu, Org. Biomol. Chem., 2018, 16, 1065
    DOI: 10.1039/C7OB03145A

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