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Intramolecular Morita–Baylis–Hillman reaction as a strategy for the construction of tricyclic sesquiterpene cores

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Abstract

Starting from a common polyfunctionalized bicyclo[3.2.1]octane-6,8-dione intermediate, a concise synthetic route to tricyclic cores found in quadrane, suberosane, cedrane and related sesquiterpenes was developed using a Morita–Baylis–Hillman intramolecular reaction as a key step.

Graphical abstract: Intramolecular Morita–Baylis–Hillman reaction as a strategy for the construction of tricyclic sesquiterpene cores

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Publication details

The article was received on 18 Dec 2017, accepted on 30 Jan 2018 and first published on 30 Jan 2018


Article type: Paper
DOI: 10.1039/C7OB03124F
Citation: Org. Biomol. Chem., 2018, Advance Article
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    Intramolecular Morita–Baylis–Hillman reaction as a strategy for the construction of tricyclic sesquiterpene cores

    C. Peter, P. Geoffroy and M. Miesch, Org. Biomol. Chem., 2018, Advance Article , DOI: 10.1039/C7OB03124F

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