Jump to main content
Jump to site search


NMR and experimental reinvestigation of the condensation reaction between γ-methylene-α,β-unsaturated aldehydes and propargyl aldehydes

Author affiliations

Abstract

The condensation reaction between a γ-methylene-α,β-unsaturated aldehyde and phenylpropargyl aldehyde was revisited and, guided by extensive DFT calculations of NMR shifts, was found to afford a deconjugative aldol condensation product. In this manner, a simple protocol for the preparation of valuable cross-conjugated oxatrienes was uncovered.

Graphical abstract: NMR and experimental reinvestigation of the condensation reaction between γ-methylene-α,β-unsaturated aldehydes and propargyl aldehydes

Back to tab navigation

Supplementary files

Publication details

The article was received on 15 Dec 2017, accepted on 24 Jan 2018 and first published on 24 Jan 2018


Article type: Communication
DOI: 10.1039/C7OB03110F
Citation: Org. Biomol. Chem., 2018, Advance Article
  •   Request permissions

    NMR and experimental reinvestigation of the condensation reaction between γ-methylene-α,β-unsaturated aldehydes and propargyl aldehydes

    M. J. Riveira and A. M. Sarotti, Org. Biomol. Chem., 2018, Advance Article , DOI: 10.1039/C7OB03110F

Search articles by author

Spotlight

Advertisements