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Issue 6, 2018
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Nickel-catalyzed cross-coupling of β-carbonyl alkenyl pivalates with arylzinc chlorides

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Abstract

The nickel-catalyzed cross-coupling reaction of β-carbonyl alkenyl pivalates with arylzinc reagents generates 3-aryl-substituted α,β-unsaturated carbonyl compounds via C–O bond cleavage. The reaction features mild reaction conditions, a wide scope of substrates, and good functional group tolerance.

Graphical abstract: Nickel-catalyzed cross-coupling of β-carbonyl alkenyl pivalates with arylzinc chlorides

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Publication details

The article was received on 29 Nov 2017, accepted on 08 Jan 2018 and first published on 08 Jan 2018


Article type: Paper
DOI: 10.1039/C7OB02947K
Citation: Org. Biomol. Chem., 2018,16, 1029-1036
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    Nickel-catalyzed cross-coupling of β-carbonyl alkenyl pivalates with arylzinc chlorides

    W. Pan and Z. Wang, Org. Biomol. Chem., 2018, 16, 1029
    DOI: 10.1039/C7OB02947K

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