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Issue 3, 2018
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Exploring bis-(amino)cyclopropenylidene as a non-covalent Brønsted base catalyst in conjugate addition reactions

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Abstract

Bis-(amino)cyclopropenylidene has been utilised as a non-covalent Brønsted base catalyst in the 1,6-conjugate addition of carbon nucleophiles to p-QMs. This protocol makes it possible to access unsymmetrical diaryl- and triarylmethanes in good to excellent yields. Further, this catalyst was also explored in the 1,4-conjugate addition of carbon nucleophiles to enone systems.

Graphical abstract: Exploring bis-(amino)cyclopropenylidene as a non-covalent Brønsted base catalyst in conjugate addition reactions

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Publication details

The article was received on 22 Nov 2017, accepted on 11 Dec 2017 and first published on 11 Dec 2017


Article type: Communication
DOI: 10.1039/C7OB02882B
Citation: Org. Biomol. Chem., 2018,16, 384-388
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    Exploring bis-(amino)cyclopropenylidene as a non-covalent Brønsted base catalyst in conjugate addition reactions

    G. Singh, P. Goswami and R. Vijaya Anand, Org. Biomol. Chem., 2018, 16, 384
    DOI: 10.1039/C7OB02882B

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