Issue 2, 2018

Stereocontrolled glycoside synthesis by activation of glycosyl sulfone donors with scandium(iii) triflate

Abstract

The activation of aryl glycosyl sulfone donors has been achieved using scandium(III) triflate and has led to the selective preparation of α-mannosides resulting from a post-glycosylation anomerization.

Graphical abstract: Stereocontrolled glycoside synthesis by activation of glycosyl sulfone donors with scandium(iii) triflate

Supplementary files

Article information

Article type
Paper
Submitted
14 Nov 2017
Accepted
12 Dec 2017
First published
12 Dec 2017

Org. Biomol. Chem., 2018,16, 325-335

Stereocontrolled glycoside synthesis by activation of glycosyl sulfone donors with scandium(III) triflate

A. Xolin, R. Losa, A. Kaid, C. Tresse, J. Beau, F. Boyer and S. Norsikian, Org. Biomol. Chem., 2018, 16, 325 DOI: 10.1039/C7OB02792C

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