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Ultrafast Growth of Horizontal GaN Nanowires by HVPE through Flipping the Substrate


Recently, horizontal nanowires (NWs) have attracted much attention due to their increased compatibility with NWs-based integrated nanoelectronics and nanophotonics system. To date, however, it still remains challenging to synthesize horizontal NWs efficiently. Here we introduce a novel method towards controllable growth of horizontal GaN NWs using HVPE with an Au/Ni thin film as the catalyst. By simply flipping the substrate, horizontal GaN NWs with various growth directions and cross sections have been obtained on sapphire substrate with various facet orientations. Benefiting from the high decomposition frequency of GaCl precursors, the growth rate for the horizontal NWs is as fast as 400 μ/h. Our results show that the facing orientation of the loaded substrate affects the flow of local precursor, which determines the growth mode of the GaN NWs, i.e., no matter the substrate is facing downward or upwards. Photoluminescence measurements of the horizontal NWs show a finite blue shift of the near band edge-related emission. It indicates the presence of compressed stress and is confirmed by the geometrical phase analysis (GPA) further. Our work opens a new route and sheds light on the horizontal GaN NWs and will advance the development of horizontal NWs based nanoelectronics and nanophotonics device and system.

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Publication details

The article was accepted on 04 Feb 2018 and first published on 09 Feb 2018

Article type: Paper
DOI: 10.1039/C8NR00175H
Citation: Nanoscale, 2018, Accepted Manuscript
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    Ultrafast Growth of Horizontal GaN Nanowires by HVPE through Flipping the Substrate

    W. shaoteng, L. Wang, Z. liu, X. Yi, Y. huang, C. Yang, T. Wei, J. Yan, G. Yuan, J. Wang and J. Li, Nanoscale, 2018, Accepted Manuscript , DOI: 10.1039/C8NR00175H

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