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Controlled synthesis of organic single-crystalline nanowires via the synergy approach of the bottom-up/top-down processes

Abstract

The controlled fabrication of organic single-crystalline nanowires (OSCNWs) with the uniform diameter in nanoscale via the bottom-up approach, which is just based on the weak intermolecular interaction, is a great challenge. Herein, we utilize the synergy approach of the bottom-up and the top-down processes to fabricate the OSCNWs with diameters of 120 ± 10 nm through the stepwise evolution processes. Specifically, the evolved processes vary from the self-assembled organic micro-rods with quadrangular pyramid-like end-structure bounded with {111}s and {11-1}s crystal planes, to the “top-down” synthesized organic micro-rods with the flat cross-sectional {002}s plane, to the organic micro-tubes with a wall thickness of ~115 nm, and finally to the organic nanowires. Notably, the anisotropic etching process caused by the protic solvent molecules (such as ethanol) is crucial for the evolved morphology throughout the whole top-down process. Therefore, our demonstration opens a new venue for the controlled-fabrication of organic nanowires, and also contributes to the development of nanowires-based organic optoelectronics such as organic nanowire lasers.

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Publication details

The article was received on 30 Nov 2017, accepted on 05 Feb 2018 and first published on 06 Feb 2018


Article type: Paper
DOI: 10.1039/C7NR08931G
Citation: Nanoscale, 2018, Accepted Manuscript
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    Controlled synthesis of organic single-crystalline nanowires via the synergy approach of the bottom-up/top-down processes

    M. Zhuo, Y. Zhang, Z. Li, Y. Shi, X. Wang and L. Liao, Nanoscale, 2018, Accepted Manuscript , DOI: 10.1039/C7NR08931G

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