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Quantifying Atom-scale Dopant Movement and Electrical Activation in Si:P Monolayers


Advanced hydrogen lithography techniques and low-temperature epitaxial overgrowth enable patterning of highly phosphorus-doped silicon (Si:P) monolayers (ML) with atomic precision. This approach to device fabrication has made Si:P monolayer systems a testbed for multiqubit quantum computing architectures and atomically precise 2-D superlattice designs whose behaviors are directly tied to the deterministic placement of single dopants. However, dopant segregation, diffusion, surface roughening, and defect formation during the encapsulation overgrowth introduce large uncertainties to the exact dopant placement and activation ratio. In this study, we develop a unique method by combining dopant segregation/diffusion models with sputter profiling simulation to monitor and control, at the atomic scale, dopant movement using room-temperature grown locking layers (LL). We explore the impact of LL growth rate, thickness, rapid thermal anneal, surface accumulation, and growth front roughness on dopant confinement, local crystalline quality, and electrical activation within Si:P 2-D systems We demonstrate that dopant movement can be more efficiently suppressed by increasing the LL growth rate than by increasing LL thickness. We find that the dopant segregation length can be suppressed below a single Si lattice constant by increasing LL growth rates at room temperature while maintaining epitaxy. Although dopant diffusivity within the LL is found to remain high (on the order of 10-17 cm2/s) even below the hydrogen desorption temperature, we demonstrate that exceptionally sharp dopant confinement with high electrical quality within Si:P monolayers can be achieved by combining a high LL growth rate with a low-temperature LL rapid thermal anneal. The method developed in this study provides a key tool for 2-D fabrication techniques that require precise dopant placement to suppress, quantify, and predict a single dopant’s movement at the atomic scale.

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Publication details

The article was received on 19 Oct 2017, accepted on 25 Jan 2018 and first published on 26 Jan 2018

Article type: Paper
DOI: 10.1039/C7NR07777G
Citation: Nanoscale, 2018, Accepted Manuscript
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    Quantifying Atom-scale Dopant Movement and Electrical Activation in Si:P Monolayers

    X. Wang, J. A. Hagmann, P. Namboodiri, J. Wyrick, K. Li, R. Murray, A. Myers, F. Misenkosen, M. D. Stewart, C. A. Richter and R. Silver, Nanoscale, 2018, Accepted Manuscript , DOI: 10.1039/C7NR07777G

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