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Issue 6, 2018
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Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids

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Abstract

Covering: up to the end of 2017

Enantioselective Pd-catalyzed allylic alkylations of prochiral enolates represent a powerful tool for the construction of all-carbon quaternary stereocenters. This review describes the emergence of such reactions as strategic linchpins that enable efficient, stereocontrolled syntheses of Aspidosperma and related monoterpene indole alkaloids.

Graphical abstract: Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids

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Publication details

The article was received on 23 Dec 2017 and first published on 16 Apr 2018


Article type: Review Article
DOI: 10.1039/C7NP00069C
Citation: Nat. Prod. Rep., 2018,35, 559-574
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    Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids

    B. P. Pritchett and B. M. Stoltz, Nat. Prod. Rep., 2018, 35, 559
    DOI: 10.1039/C7NP00069C

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