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Highly active NHC–Pd(II) complexes for cross coupling of aryl chlorides and arylboronic acids: an investigation of the effect of remote bulky groups

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Abstract

A series of palladium(II) complexes bearing remote bulky ligands were synthesized and characterized. Their catalytic activity for Suzuki–Miyaura cross-coupling reactions and the effect of remote bulky groups were investigated. These new palladium complexes are highly efficient for the Suzuki–Miyaura cross-coupling reactions of aryl chlorides and arylboronic acids with low catalyst loadings (0.05 mol%) at room temperature in air.

Graphical abstract: Highly active NHC–Pd(ii) complexes for cross coupling of aryl chlorides and arylboronic acids: an investigation of the effect of remote bulky groups

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Publication details

The article was received on 03 Mar 2018, accepted on 29 Mar 2018 and first published on 06 Apr 2018


Article type: Paper
DOI: 10.1039/C8NJ01047A
Citation: New J. Chem., 2018, Advance Article
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    Highly active NHC–Pd(II) complexes for cross coupling of aryl chlorides and arylboronic acids: an investigation of the effect of remote bulky groups

    F. Han, Y. Xu, R. Zhu, G. Liu, C. Chen and J. Wang, New J. Chem., 2018, Advance Article , DOI: 10.1039/C8NJ01047A

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