Jump to main content
Jump to site search

Issue 11, 2018
Previous Article Next Article

Synthesis, characterization, and reactivity of a chiral Fe(IV)–oxo complex bearing an L-proline-derived aminopyridine ligand

Author affiliations

Abstract

A novel nonheme chiral Fe(IV)–oxo complex bearing an L-proline-derived aminopyridine was synthesized and spectroscopically characterized by UV-vis, CSI-TOF MS and EPR. The appropriate half-life of about 1 h at 0 °C allows us to study its reactivity in the C–H activation of various hydrocarbons in detail. In addition, its reactivity in asymmetric sulfoxidation and C–H hydroxylation was also investigated.

Graphical abstract: Synthesis, characterization, and reactivity of a chiral Fe(iv)–oxo complex bearing an l-proline-derived aminopyridine ligand

Back to tab navigation

Supplementary files

Publication details

The article was received on 27 Feb 2018, accepted on 09 Apr 2018 and first published on 10 Apr 2018


Article type: Letter
DOI: 10.1039/C8NJ00964C
Citation: New J. Chem., 2018,42, 8315-8319
  •   Request permissions

    Synthesis, characterization, and reactivity of a chiral Fe(IV)–oxo complex bearing an L-proline-derived aminopyridine ligand

    J. Du, J. Zhang, J. Zhu, C. Xia and W. Sun, New J. Chem., 2018, 42, 8315
    DOI: 10.1039/C8NJ00964C

Search articles by author

Spotlight

Advertisements