Synthesis, characterization, and reactivity of a chiral Fe(IV)–oxo complex bearing an L-proline-derived aminopyridine ligand

Junyi Du; Jisheng Zhang; Jianhua Zhu; Chungu Xia; Wei Sun

doi:10.1039/C8NJ00964C

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Synthesis, characterization, and reactivity of a chiral Fe(iv)–oxo complex bearing an l-proline-derived aminopyridine ligand†

Junyi Du,^ab Jisheng Zhang,^a Jianhua Zhu,^a Chungu Xia^a and Wei Sun

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory for Oxo Synthesis and Selective Oxidation, Center for Excellence in Molecular Synthesis, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou, P. R. China
E-mail: wsun@licp.cas.cn

^b University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

A novel nonheme chiral Fe(IV)–oxo complex bearing an L-proline-derived aminopyridine was synthesized and spectroscopically characterized by UV-vis, CSI-TOF MS and EPR. The appropriate half-life of about 1 h at 0 °C allows us to study its reactivity in the C–H activation of various hydrocarbons in detail. In addition, its reactivity in asymmetric sulfoxidation and C–H hydroxylation was also investigated.

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DOI: https://doi.org/10.1039/C8NJ00964C
Article type: Letter
Submitted: 27 Feb 2018
Accepted: 09 Apr 2018
First published: 10 Apr 2018

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New J. Chem., 2018,42, 8315-8319

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Synthesis, characterization, and reactivity of a chiral Fe(IV)–oxo complex bearing an L-proline-derived aminopyridine ligand

J. Du, J. Zhang, J. Zhu, C. Xia and W. Sun, New J. Chem., 2018, 42, 8315 DOI: 10.1039/C8NJ00964C

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New Journal of Chemistry

Synthesis, characterization, and reactivity of a chiral Fe(iv)–oxo complex bearing an l-proline-derived aminopyridine ligand†

Abstract

Supplementary files

Article information

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Synthesis, characterization, and reactivity of a chiral Fe(IV)–oxo complex bearing an L-proline-derived aminopyridine ligand

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