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Synthesis, characterization, and reactivity of a chiral Fe(IV)-oxo complex bearing an L-proline derived aminopyridine ligand

Abstract

A novel nonheme chiral Fe(IV)-oxo complex bearing an L-proline derived aminopyridine was synthesized and spectroscopically characterized by UV-vis, CSI-TOF MS and EPR. The appropriate half-life about 1 h at 0 °C allows us to detailedly study its reactivity in C-H activation of various hydrocarbons. In addition, its reactivity in asymmetric sulfoxidation and C-H hydroxylation was also investigated.

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Publication details

The article was received on 27 Feb 2018, accepted on 09 Apr 2018 and first published on 10 Apr 2018


Article type: Letter
DOI: 10.1039/C8NJ00964C
Citation: New J. Chem., 2018, Accepted Manuscript
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    Synthesis, characterization, and reactivity of a chiral Fe(IV)-oxo complex bearing an L-proline derived aminopyridine ligand

    J. Du, J. Zhang, J. Zhu, C. Xia and W. Sun, New J. Chem., 2018, Accepted Manuscript , DOI: 10.1039/C8NJ00964C

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