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Halogen bonding two-point recognition with terphenyl derivatives

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Abstract

Two-point recognition involving neutral terphenyl-based halogen bond donors (halogen-based Lewis acids) was investigated. Oxadiazole and pyridazole derivatives were identified by DFT as suitable binding partners, even though gas-phase binding was weak. X-ray studies provided convincing evidence of two-point binding in the solid state, while solution data hinted at weak association.

Graphical abstract: Halogen bonding two-point recognition with terphenyl derivatives

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Publication details

The article was received on 26 Feb 2018, accepted on 06 Apr 2018 and first published on 12 Apr 2018


Article type: Letter
DOI: 10.1039/C8NJ00962G
Citation: New J. Chem., 2018, Advance Article
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    Halogen bonding two-point recognition with terphenyl derivatives

    J. Stoesser, G. Rojas, D. Bulfield, P. I. Hidalgo, J. Pasán, C. Ruiz-Pérez, C. A. Jiménez and S. M. Huber, New J. Chem., 2018, Advance Article , DOI: 10.1039/C8NJ00962G

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