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Revisit of 1 Chloro-1,2-benziodoxol-3-one: Efficient ortho-Chlorination of aryls under aqueous conditions.

Abstract

The application of 1-chloro-1,2-benziodoxol-3-one as a powerful chlorinating agent on aniline derivatives is explored. The amide directing group assisted radical mediated ortho-selective chlorination proceeds in the absence of radical initiator. Various electronically differentiated anilides and sulfonamides are tolerated under aqueous conditions.

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Publication details

The article was received on 30 Jan 2018, accepted on 11 Apr 2018 and first published on 12 Apr 2018


Article type: Paper
DOI: 10.1039/C8NJ00530C
Citation: New J. Chem., 2018, Accepted Manuscript
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    Revisit of 1 Chloro-1,2-benziodoxol-3-one: Efficient ortho-Chlorination of aryls under aqueous conditions.

    C. Malapaka, V. Botla, V. R. Pardhi and R. V. Daggupati, New J. Chem., 2018, Accepted Manuscript , DOI: 10.1039/C8NJ00530C

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