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Issue 11, 2018
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Revisiting 1-chloro-1,2-benziodoxol-3-one: efficient ortho-chlorination of aryls under aqueous conditions

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Abstract

The application of 1-chloro-1,2-benziodoxol-3-one as a powerful chlorinating agent as well as oxidant for aniline derivatives is explored. The amide directing group assisted radical mediated ortho-selective chlorination proceeds in the absence of a radical initiator. Various electronically differentiated anilides and sulfonamides are tolerated under aqueous conditions.

Graphical abstract: Revisiting 1-chloro-1,2-benziodoxol-3-one: efficient ortho-chlorination of aryls under aqueous conditions

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Publication details

The article was received on 30 Jan 2018, accepted on 11 Apr 2018 and first published on 12 Apr 2018


Article type: Paper
DOI: 10.1039/C8NJ00530C
Citation: New J. Chem., 2018,42, 8953-8959
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    Revisiting 1-chloro-1,2-benziodoxol-3-one: efficient ortho-chlorination of aryls under aqueous conditions

    B. Vinayak, P. V. Ravindrakumar, D. V. Ramana and M. Chandrasekharam, New J. Chem., 2018, 42, 8953
    DOI: 10.1039/C8NJ00530C

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