Jump to main content
Jump to site search

Issue 13, 2018
Previous Article Next Article

Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt

Author affiliations

Abstract

We have prepared 3-Cl-10-I-nido-7,8,9,11-P2C2B7H7 by the reaction of 3-Cl-nido-7,8,9,11-P2C2B7H8 with I2 in the presence of AlCl3. The product was obtained in a yield of 49% and was characterized by NMR spectroscopy and X-ray crystallography. Quantum chemical calculations have demonstrated that the crystal structure is stabilized by hydrogen, dihydrogen and pnictogen bonds.

Graphical abstract: Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt

Back to tab navigation

Supplementary files

Publication details

The article was received on 25 Jan 2018, accepted on 19 Mar 2018 and first published on 29 Mar 2018


Article type: Letter
DOI: 10.1039/C8NJ00450A
Citation: New J. Chem., 2018,42, 10481-10483
  • Open access: Creative Commons BY-NC license
  •   Request permissions

    Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt

    J. Holub, Z. Růžičková, P. Hobza, J. Fanfrlík, D. Hnyk and A. Růžička, New J. Chem., 2018, 42, 10481
    DOI: 10.1039/C8NJ00450A

    This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material and it is not used for commercial purposes.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements