Jump to main content
Jump to site search


Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt

Author affiliations

Abstract

We have prepared 3-Cl-10-I-nido-7,8,9,11-P2C2B7H7 by the reaction of 3-Cl-nido-7,8,9,11-P2C2B7H8 with I2 in the presence of AlCl3. The product was obtained in a yield of 49% and was characterized by NMR spectroscopy and X-ray crystallography. Quantum chemical calculations have demonstrated that the crystal structure is stabilized by hydrogen, dihydrogen and pnictogen bonds.

Graphical abstract: Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt

Back to tab navigation

Supplementary files

Publication details

The article was received on 25 Jan 2018, accepted on 19 Mar 2018 and first published on 29 Mar 2018


Article type: Letter
DOI: 10.1039/C8NJ00450A
Citation: New J. Chem., 2018, Advance Article
  •   Request permissions

    Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt

    J. Holub, Z. Růžičková, P. Hobza, J. Fanfrlík, D. Hnyk and A. Růžička, New J. Chem., 2018, Advance Article , DOI: 10.1039/C8NJ00450A

Search articles by author

Spotlight

Advertisements