Investigation on the physicochemical properties of Ce0.8Eu0.1M0.1O2−δ (M = Zr, Hf, La, and Sm) solid solutions towards soot combustion

Abstract

This investigation focuses on the manipulation of the physicochemical properties and oxygen defect concentration of europium doped CeO₂ by the introduction of a second dopant (co-dopant, M). Accordingly, in this study a series of Ce_0.8Eu_0.1M_0.1O_2−δ (M = Zr, Hf, La, and Sm) nano-oxides were prepared and tested for diesel soot oxidation catalysis. The systematic characterization studies indicated successful incorporation of both dopants in the cubic fluorite crystal structure of CeO₂. A remarkable enhancement in the reduction properties and oxygen defect concentration was observed for the co-doped samples from structural and chemical analyses. The aliovalent co-doped materials exhibited better performance than the isovalent co-doped materials. The catalytic activity order of the prepared materials towards model soot oxidation was Ce_0.8Eu_0.1La_0.1O_2−δ > Ce_0.8Eu_0.1Sm_0.1O_2−δ > Ce_0.8Eu_0.1Hf_0.1O_2−δ > Ce_0.8Eu_0.1Zr_0.1O_2−δ > Ce_0.9Eu_0.1O_2−δ > CeO₂. The most favorable modification of the physicochemical properties of europium doped ceria was ascertained in the presence of La as a co-dopant compared to other combinations investigated. The correlation of the physicochemical properties with the catalytic activity has also been clearly demonstrated in the manuscript.