Jump to main content
Jump to site search

Issue 8, 2018
Previous Article Next Article

Non-covalent tetrel bonding interactions in hemidirectional lead(II) complexes with nickel(II)-salen type metalloligands

Author affiliations

Abstract

Four hetero-dinuclear nickel(II)/lead(II) complexes have been synthesized and characterized. Their structures have been confirmed by single crystal X-ray diffraction studies. In each complex, nickel(II) is placed in the inner N2O2 compartment and lead(II) in the outer O2O2′ compartment of the respective Schiff base. In complexes 1, 3 and 4, lead(II) centres are hemidirectionally coordinated, and thus are well suited for establishing tetrel bonding interactions which have been investigated thoroughly by means of DFT calculations.

Graphical abstract: Non-covalent tetrel bonding interactions in hemidirectional lead(ii) complexes with nickel(ii)-salen type metalloligands

Back to tab navigation

Supplementary files

Publication details

The article was received on 27 Dec 2017, accepted on 26 Feb 2018 and first published on 26 Feb 2018


Article type: Paper
DOI: 10.1039/C7NJ05148D
Citation: New J. Chem., 2018,42, 6062-6076
  •   Request permissions

    Non-covalent tetrel bonding interactions in hemidirectional lead(II) complexes with nickel(II)-salen type metalloligands

    S. Roy, M. G. B. Drew, A. Bauzá, A. Frontera and S. Chattopadhyay, New J. Chem., 2018, 42, 6062
    DOI: 10.1039/C7NJ05148D

Search articles by author

Spotlight

Advertisements