Issue 8, 2018

Non-covalent tetrel bonding interactions in hemidirectional lead(ii) complexes with nickel(ii)-salen type metalloligands

Abstract

Four hetero-dinuclear nickel(II)/lead(II) complexes have been synthesized and characterized. Their structures have been confirmed by single crystal X-ray diffraction studies. In each complex, nickel(II) is placed in the inner N2O2 compartment and lead(II) in the outer O2O2′ compartment of the respective Schiff base. In complexes 1, 3 and 4, lead(II) centres are hemidirectionally coordinated, and thus are well suited for establishing tetrel bonding interactions which have been investigated thoroughly by means of DFT calculations.

Graphical abstract: Non-covalent tetrel bonding interactions in hemidirectional lead(ii) complexes with nickel(ii)-salen type metalloligands

Supplementary files

Article information

Article type
Paper
Submitted
27 Dec 2017
Accepted
26 Feb 2018
First published
26 Feb 2018

New J. Chem., 2018,42, 6062-6076

Non-covalent tetrel bonding interactions in hemidirectional lead(II) complexes with nickel(II)-salen type metalloligands

S. Roy, M. G. B. Drew, A. Bauzá, A. Frontera and S. Chattopadhyay, New J. Chem., 2018, 42, 6062 DOI: 10.1039/C7NJ05148D

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