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Issue 6, 2018
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Amine-functionalized MIL-101(Cr) embedded with Co(II) phthalocyanine as a durable catalyst for one-pot tandem oxidative A3 coupling reactions of alcohols

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Abstract

A novel porous postsynthetic-modified metal–organic framework (MIL-101(Cr)-NH2) was fabricated via covalent immobilization of cobalt(II) phthalocyanine and characterized by a variety of techniques, including FTIR, XRD, TGA, SEM, EDS and ICP-OES analyses. This catalyst was successfully used in one-pot tandem oxidative A3 coupling reactions of alcohols. The main advantages of this protocol are the reusability of the catalyst, operational simplicity, mild reaction conditions and high yields.

Graphical abstract: Amine-functionalized MIL-101(Cr) embedded with Co(ii) phthalocyanine as a durable catalyst for one-pot tandem oxidative A3 coupling reactions of alcohols

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Publication details

The article was received on 26 Dec 2017, accepted on 03 Feb 2018 and first published on 05 Feb 2018


Article type: Paper
DOI: 10.1039/C7NJ05132H
Citation: New J. Chem., 2018,42, 4167-4174
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    Amine-functionalized MIL-101(Cr) embedded with Co(II) phthalocyanine as a durable catalyst for one-pot tandem oxidative A3 coupling reactions of alcohols

    A. Shaabani, R. Mohammadian, A. Hashemzadeh, R. Afshari and M. M. Amini, New J. Chem., 2018, 42, 4167
    DOI: 10.1039/C7NJ05132H

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