Issue 6, 2018

Sulphur dioxide cooperation in hydrolysis reactions of vanadium oxide and hydroxide cluster dianions

Abstract

Unprecedented hydrolysis reactions are observed in the gas phase in clusters containing doubly-charged vanadium oxides and hydroxide anions, SO2 and H2O. The experimental and computational study shows the cooperative effects of the vanadium species, V2O62− and HV3O92−, and sulfur dioxide on the enhancement of the hydrogen bonds of water that allows the acid–base reaction and charge separation in the doubly-charged ion.

Graphical abstract: Sulphur dioxide cooperation in hydrolysis reactions of vanadium oxide and hydroxide cluster dianions

Supplementary files

Article information

Article type
Paper
Submitted
18 Dec 2017
Accepted
24 Jan 2018
First published
25 Jan 2018

New J. Chem., 2018,42, 4008-4016

Sulphur dioxide cooperation in hydrolysis reactions of vanadium oxide and hydroxide cluster dianions

A. Troiani, M. Rosi, S. Garzoli, C. Salvitti and G. de Petris, New J. Chem., 2018, 42, 4008 DOI: 10.1039/C7NJ05011A

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