Jump to main content
Jump to site search

Issue 6, 2018
Previous Article Next Article

Sulphur dioxide cooperation in hydrolysis reactions of vanadium oxide and hydroxide cluster dianions

Author affiliations

Abstract

Unprecedented hydrolysis reactions are observed in the gas phase in clusters containing doubly-charged vanadium oxides and hydroxide anions, SO2 and H2O. The experimental and computational study shows the cooperative effects of the vanadium species, V2O62− and HV3O92−, and sulfur dioxide on the enhancement of the hydrogen bonds of water that allows the acid–base reaction and charge separation in the doubly-charged ion.

Graphical abstract: Sulphur dioxide cooperation in hydrolysis reactions of vanadium oxide and hydroxide cluster dianions

Back to tab navigation

Supplementary files

Publication details

The article was received on 18 Dec 2017, accepted on 24 Jan 2018 and first published on 25 Jan 2018


Article type: Paper
DOI: 10.1039/C7NJ05011A
Citation: New J. Chem., 2018,42, 4008-4016
  •   Request permissions

    Sulphur dioxide cooperation in hydrolysis reactions of vanadium oxide and hydroxide cluster dianions

    A. Troiani, M. Rosi, S. Garzoli, C. Salvitti and G. de Petris, New J. Chem., 2018, 42, 4008
    DOI: 10.1039/C7NJ05011A

Search articles by author

Spotlight

Advertisements