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Iodine/DMSO oxidations: a contemporary paradigm in C–N bond chemistry

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Abstract

A new era in the organic synthetic world is demanding greener protocols for the execution of reactions. As the world is progressing towards fewer natural resources and high energy input, organic chemists are keeping a strict eye on seeking alternative methods to rise above these difficult situations. Amongst all reactions, oxidative reactions are the ones which require the major use of expensive metals, and harsh and toxic reagents owing to which the need of the green hour indispensably calls for a contemporary solution to existing conventional methodologies. Hereby, this review talks about the combined role of molecular iodine and DMSO in revolutionizing synthetic methodologies, especially reactions related to the oxidation process. In particular, this review highlights the construction of the C–N bond in forging biologically potent molecules through this indispensable tool.

Graphical abstract: Iodine/DMSO oxidations: a contemporary paradigm in C–N bond chemistry

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Publication details

The article was received on 20 Nov 2017, accepted on 30 Dec 2017 and first published on 02 Jan 2018


Article type: Perspective
DOI: 10.1039/C7NJ04513A
Citation: New J. Chem., 2018, Advance Article
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    Iodine/DMSO oxidations: a contemporary paradigm in C–N bond chemistry

    A. Monga, S. Bagchi and A. Sharma, New J. Chem., 2018, Advance Article , DOI: 10.1039/C7NJ04513A

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