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Issue 3, 2018
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Synthesis of a heterogeneous Cu(OAc)2-anchored SBA-15 catalyst and its application in the CuAAC reaction

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Abstract

A novel dinuclear Cu(OAc)2-anchored SBA-15 catalyst was synthesized by simple proton exchange of a carboxyl functionalized mesoporous SBA-15 silica with Cu(OAc)2 in water. XAFS and EPR spectra were utilized to probe its structure. Such a Cu(II) solid material exhibited excellent catalytic activity for the azide–alkyne cycloaddition reaction in water without addition of either reductant or base.

Graphical abstract: Synthesis of a heterogeneous Cu(OAc)2-anchored SBA-15 catalyst and its application in the CuAAC reaction

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Publication details

The article was received on 19 Nov 2017, accepted on 08 Jan 2018 and first published on 10 Jan 2018


Article type: Letter
DOI: 10.1039/C7NJ04495J
Citation: New J. Chem., 2018,42, 1612-1616
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    Synthesis of a heterogeneous Cu(OAc)2-anchored SBA-15 catalyst and its application in the CuAAC reaction

    N. Sun, Z. Yu, H. Yi, X. Zhu, L. Jin, B. Hu, Z. Shen and X. Hu, New J. Chem., 2018, 42, 1612
    DOI: 10.1039/C7NJ04495J

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