Jump to main content
Jump to site search

Issue 2, 2018
Previous Article Next Article

Synthesis, structures and magnetic properties of linear {CoII2LnIII2} coordination clusters

Author affiliations

Abstract

Three linear heterometallic CoII2LnIII2 (Ln = Dy (1), Gd (2), Y (3)) coordination clusters have been synthesized under solvothermal conditions. Single-crystal X-ray diffraction studies revealed that all three compounds are isostructural and crystallize in the monoclinic space group P21/c with Z = 2. The dc magnetic susceptibilities for all three compounds have been measured and the magnetic exchange couplings (for 2) and magnetic anisotropy for CoII ions (for 2 and 3) have been calculated and discussed. Furthermore, the ac magnetic susceptibility measurements have been performed and show that CoII2DyIII2 compounds 1 display single-molecule magnetic (SMM) behavior.

Graphical abstract: Synthesis, structures and magnetic properties of linear {CoII2LnIII2} coordination clusters

Back to tab navigation

Supplementary files

Publication details

The article was received on 18 Oct 2017, accepted on 12 Dec 2017 and first published on 13 Dec 2017


Article type: Paper
DOI: 10.1039/C7NJ04022A
Citation: New J. Chem., 2018,42, 1284-1289
  •   Request permissions

    Synthesis, structures and magnetic properties of linear {CoII2LnIII2} coordination clusters

    S. Chen, V. Mereacre, Z. Zhao, W. Zhang and Z. He, New J. Chem., 2018, 42, 1284
    DOI: 10.1039/C7NJ04022A

Search articles by author

Spotlight

Advertisements