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Copper-catalyzed α-C–H acyloxylation of carbonyl compounds with terminal alkynes

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Abstract

Herein, a copper/TBHP catalyst system for the α-C–H acyloxylation of carbonyl compounds is developed using terminal alkynes as the acyloxy source. A variety of carbonyl compounds and terminal alkynes are tolerated in this reaction. In addition, its possible mechanism is proposed.

Graphical abstract: Copper-catalyzed α-C–H acyloxylation of carbonyl compounds with terminal alkynes

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Publication details

The article was received on 16 Oct 2017, accepted on 21 Dec 2017 and first published on 05 Jan 2018


Article type: Letter
DOI: 10.1039/C7NJ03989A
Citation: New J. Chem., 2018, Advance Article
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    Copper-catalyzed α-C–H acyloxylation of carbonyl compounds with terminal alkynes

    J. Li, Z. Yang, T. Yang, J. Yi and C. Zhou, New J. Chem., 2018, Advance Article , DOI: 10.1039/C7NJ03989A

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