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Issue 2, 2018
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Templated metalophilicity: synthesis of halometallic double salts directed by a dicopper(I) hydrazinyl-tetraimine nanocation

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Abstract

A nanometric size dication [Cu2(dih)2]2+ (where dih – 1,2-di[[2-(pyridin-2-yl)hydrazin-1-ylidene]methyl]benzene) of a molecular volume of 0.5 nm3 is described. The solvothermal synthesis and crystal structures of a new class of inclusion double salts, exhibiting d10–d10 and d10–d5 metallophilicity, of the formula [Cu2(dih)2]2[Cu(4 − y)MyCl8], where M is either Cu+ or heterometal of valency y (in this paper Mn2+ or La3+), are reported. UV-vis spectroscopy and square-wave voltammetry complement the characterisation of the luminescent salts.

Graphical abstract: Templated metalophilicity: synthesis of halometallic double salts directed by a dicopper(i) hydrazinyl-tetraimine nanocation

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Publication details

The article was received on 11 Oct 2017, accepted on 08 Dec 2017 and first published on 11 Dec 2017


Article type: Letter
DOI: 10.1039/C7NJ03919K
Citation: New J. Chem., 2018,42, 817-821
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    Templated metalophilicity: synthesis of halometallic double salts directed by a dicopper(I) hydrazinyl-tetraimine nanocation

    P. Zabierowski, M. Hodorowicz and J. Szklarzewicz, New J. Chem., 2018, 42, 817
    DOI: 10.1039/C7NJ03919K

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