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Issue 2, 2018
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The synthesis of arylcyanamides: a copper-catalyzed consecutive desulfurization and C–N cross-coupling strategy

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Abstract

A one pot highly efficient and simple protocol for the construction of aromatic cyanamides from thiourea via desulphurization/C–N cross coupling using a cheap, readily available and air stable copper source as a catalyst has been described. Various iodobenzenes could give their respective C–N cross-coupled products in good to excellent yields under optimized reaction conditions. Further, the substrate scope has been explored.

Graphical abstract: The synthesis of arylcyanamides: a copper-catalyzed consecutive desulfurization and C–N cross-coupling strategy

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Publication details

The article was received on 15 Sep 2017, accepted on 28 Nov 2017 and first published on 11 Dec 2017


Article type: Paper
DOI: 10.1039/C7NJ03527F
Citation: New J. Chem., 2018,42, 918-922
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    The synthesis of arylcyanamides: a copper-catalyzed consecutive desulfurization and C–N cross-coupling strategy

    S. N. M. Boddapati, N. Polam, B. R. Mutchu and H. B. Bollikolla, New J. Chem., 2018, 42, 918
    DOI: 10.1039/C7NJ03527F

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