Issue 16, 2018

Deoxygenation of triglycerides by silylation under exceptionally mild conditions

Abstract

The reduction or decarbonylation of triglycerides to form valuable olefins and alkanes normally requires extremely vigorous conditions. The direct deoxygenation of triglycerides under ambient conditions using hydrosiloxanes in the presence of B(C6F5)3 occurs in high yield and without either reduction or migration of the alkene functional groups.

Graphical abstract: Deoxygenation of triglycerides by silylation under exceptionally mild conditions

Supplementary files

Article information

Article type
Communication
Submitted
27 Apr 2018
Accepted
19 Jul 2018
First published
20 Jul 2018

Green Chem., 2018,20, 3717-3721

Deoxygenation of triglycerides by silylation under exceptionally mild conditions

C. B. Gale and M. A. Brook, Green Chem., 2018, 20, 3717 DOI: 10.1039/C8GC01324A

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