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Issue 6, 2018
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Selective production of glycols from xylitol over Ru on covalent triazine frameworks – suppressing decarbonylation reactions

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Abstract

Ru on covaltent triazine frameworks (CTF) are highly active and selective catalysts for the conversion of xylitol to glycols (80% C-yield) in basic media. With increasing N-content decarbonylation reactions are suppressed leading to high glycol selectivity. The suppression can be attributed to the presence of N in the support and to metal-support interactions. The catalysts exhibit high stability and could be recycled 5 times with minor loss of activity.

Graphical abstract: Selective production of glycols from xylitol over Ru on covalent triazine frameworks – suppressing decarbonylation reactions

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Publication details

The article was received on 19 Jan 2018, accepted on 20 Feb 2018 and first published on 23 Feb 2018


Article type: Paper
DOI: 10.1039/C8GC00208H
Citation: Green Chem., 2018,20, 1316-1322
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    Selective production of glycols from xylitol over Ru on covalent triazine frameworks – suppressing decarbonylation reactions

    A. K. Beine, A. J. D. Krüger, J. Artz, C. Weidenthaler, C. Glotzbach, P. J. C. Hausoul and R. Palkovits, Green Chem., 2018, 20, 1316
    DOI: 10.1039/C8GC00208H

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