The oxygenation of 8-aminoquinoline amides by benzoyl peroxide at the C5 position in water is developed in the absence of a transition metal catalyst, affording the desired products in moderate to good yields of up to 88%. Mechanism studies reveal that the reaction would involve a radical process.
The article was received on 18 Jan 2018, accepted on 12 Apr 2018 and first published on 13 Apr 2018
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