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A KI-mediated radical anti-Markovnikov addition of simple ketones/esters to unactivated alkenes

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Abstract

A KI-mediated radical anti-Markovnikov addition of simple ketones and esters to unactivated alkenes was developed. Through this strategy, a wide range of complex carbonyl compounds can be conveniently synthesized in high selectivities. In addition, this method features high atom-economy and is transition-metal free, operationally simple and environmentally benign.

Graphical abstract: A KI-mediated radical anti-Markovnikov addition of simple ketones/esters to unactivated alkenes

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Publication details

The article was received on 13 Dec 2017, accepted on 05 Jan 2018 and first published on 08 Jan 2018


Article type: Communication
DOI: 10.1039/C7GC03745G
Citation: Green Chem., 2018, Advance Article
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    A KI-mediated radical anti-Markovnikov addition of simple ketones/esters to unactivated alkenes

    Y. Tian, C. Sun, R. X. Tan and Z. Liu, Green Chem., 2018, Advance Article , DOI: 10.1039/C7GC03745G

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