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Issue 4, 2018
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Efficient synthesis of 1,2-benzisothiazoles from o-haloarylamidines and elemental sulfur via N–S/C–S bond formation under transition-metal-free conditions

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Abstract

An efficient method for the synthesis of 1,2-benzisothiazoles from amidines and elemental sulfur via N–S/C–S bond formation under transition-metal-free conditions is described. This reaction is performed smoothly under simple conditions to give the corresponding products in good to high yields with good functional group tolerance.

Graphical abstract: Efficient synthesis of 1,2-benzisothiazoles from o-haloarylamidines and elemental sulfur via N–S/C–S bond formation under transition-metal-free conditions

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Publication details

The article was received on 30 Nov 2017, accepted on 16 Jan 2018 and first published on 18 Jan 2018


Article type: Communication
DOI: 10.1039/C7GC03599C
Citation: Green Chem., 2018,20, 827-831
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    Efficient synthesis of 1,2-benzisothiazoles from o-haloarylamidines and elemental sulfur via N–S/C–S bond formation under transition-metal-free conditions

    H. Xie, G. Li, F. Zhang, F. Xiao and G. Deng, Green Chem., 2018, 20, 827
    DOI: 10.1039/C7GC03599C

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