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Rhodium-catalyzed intermolecular C(sp3)–H amination in a purely aqueous system

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Abstract

An efficient Rh-catalyzed intermolecular C(sp3)–H amination in a purely aqueous system is developed for the first time. This methodology features environmental benignity, broad substrate scope and versatility in late-stage functionalization of several biologically important molecules. Such an oxidation protocol provides easy access to various aliphatic amine derivatives in an efficient and sustainable manner.

Graphical abstract: Rhodium-catalyzed intermolecular C(sp3)–H amination in a purely aqueous system

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Publication details

The article was received on 19 Oct 2017, accepted on 27 Nov 2017 and first published on 28 Nov 2017


Article type: Communication
DOI: 10.1039/C7GC03149A
Citation: Green Chem., 2018, Advance Article
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    Rhodium-catalyzed intermolecular C(sp3)–H amination in a purely aqueous system

    X. Lu, Y. Shi and F. Zhong, Green Chem., 2018, Advance Article , DOI: 10.1039/C7GC03149A

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