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Issue 3, 2018
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Beyond catalysis and membranes: visualizing and solving the challenge of electrode water accumulation and flooding in AEMFCs

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Abstract

A majority of anion exchange membrane fuel cells (AEMFCs) reported in the literature have been unable to achieve high current or power. A recently proposed theory is that the achievable current is largely limited by poorly balanced water during cell operation. In this work, we present convincing experimental results – coupling operando electrochemical measurements and neutron imaging – supporting this theory and allowing the amount and distribution of water, and its impact on AEMFC performance, to be quantified for the first time. We also create new electrode compositions by systematically manipulating the ionomer and carbon content in the anode catalyst layer, which allowed us to alleviate the mass transport behavior limitations of H2/O2 AEMFCs and achieve a new record-setting peak power density of 1.9 W cm−2 – a step-change to existing literature. Our efforts cast a new light on the design and optimization of AEMFCs – potentially changing the way that AEMFCs are constructed and operated.

Graphical abstract: Beyond catalysis and membranes: visualizing and solving the challenge of electrode water accumulation and flooding in AEMFCs

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Publication details

The article was received on 12 Jan 2018, accepted on 08 Feb 2018 and first published on 08 Feb 2018


Article type: Communication
DOI: 10.1039/C8EE00122G
Citation: Energy Environ. Sci., 2018,11, 551-558
  • Open access: Creative Commons BY license
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    Beyond catalysis and membranes: visualizing and solving the challenge of electrode water accumulation and flooding in AEMFCs

    T. J. Omasta, A. M. Park, J. M. LaManna, Y. Zhang, X. Peng, L. Wang, D. L. Jacobson, J. R. Varcoe, D. S. Hussey, B. S. Pivovar and W. E. Mustain, Energy Environ. Sci., 2018, 11, 551
    DOI: 10.1039/C8EE00122G

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