Issue 1, 2019

Single-molecule magnet behaviour in a Dy(iii) pentagonal bipyramidal complex with a quasi-linear Cl–Dy–Cl sequence

Abstract

We report the synthesis and magnetic investigation of a dysprosium pentagonal bipyramidal complex [Dy(THF)5Cl2][BPh4] (1) exhibiting a linear Cl–Dy–Cl sequence suitable for providing a coordination environment allowing a zero-field slow relaxation of the magnetization. Besides, the complex also shows dual luminescence originating from [BPh4] and Dy3+.

Graphical abstract: Single-molecule magnet behaviour in a Dy(iii) pentagonal bipyramidal complex with a quasi-linear Cl–Dy–Cl sequence

Supplementary files

Article information

Article type
Communication
Submitted
12 Oct 2018
Accepted
07 Nov 2018
First published
08 Nov 2018

Dalton Trans., 2019,48, 35-39

Single-molecule magnet behaviour in a Dy(III) pentagonal bipyramidal complex with a quasi-linear Cl–Dy–Cl sequence

J. Long, A. N. Selikhov, E. Mamontova, K. A. Lyssenko, Y. Guari, J. Larionova and A. A. Trifonov, Dalton Trans., 2019, 48, 35 DOI: 10.1039/C8DT04098B

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