Hysteretic spin crossover in isomeric iron(II) complexes

Mark B. Bushuev; Viktor P. Krivopalov; Elena B. Nikolaenkova; Katerina A. Vinogradova; Yuri V. Gatilov

doi:10.1039/C8DT02223B

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Hysteretic spin crossover in isomeric iron(ii) complexes†

Mark B. Bushuev,

*^ab Viktor P. Krivopalov,^c Elena B. Nikolaenkova,^c Katerina A. Vinogradova

^ab and Yuri V. Gatilov^bc

Author affiliations

* Corresponding authors

^a Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, 3, Acad. Lavrentiev Ave., Novosibirsk, Russia
E-mail: bushuev@niic.nsc.ru, mark.bushuev@gmail.com
Fax: +7 383 330 94 89
Tel: +7383 316 51 43

^b Novosibirsk State University, 2, Pirogova str., Novosibirsk, Russia

^c N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9, Acad. Lavrentiev Ave., Novosibirsk, Russia

Abstract

Two mononuclear iron(II) complexes with isomeric N,N,N-tridentate pyrimidine-based ligands were synthesized. Both complexes show reproducible hysteretic spin crossover. Low spin state to high spin state switching is cooperative due to autocatalysis.

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Article information

DOI: https://doi.org/10.1039/C8DT02223B
Article type: Communication
Submitted: 31 May 2018
Accepted: 27 Jun 2018
First published: 28 Jun 2018

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Dalton Trans., 2018,47, 9585-9591

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Hysteretic spin crossover in isomeric iron(II) complexes

M. B. Bushuev, V. P. Krivopalov, E. B. Nikolaenkova, K. A. Vinogradova and Y. V. Gatilov, Dalton Trans., 2018, 47, 9585 DOI: 10.1039/C8DT02223B

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Dalton Transactions

Hysteretic spin crossover in isomeric iron(ii) complexes†

Abstract

Supplementary files

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Hysteretic spin crossover in isomeric iron(II) complexes

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