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Issue 28, 2018
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Organometallic functionalized non-classical polyoxometalates: synthesis, characterization and electrochemical properties

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Abstract

Two monomeric non-classical tellurium-containing heteropolymolybdate-supported metal carbonyl derivatives (NH4)5H3{[Te2Mo12(OH)O44][Mn(CO)3]}·18H2O (1) and (NH4)8{[Te2Mo12(OH)O44][Re(CO)3]}·13H2O (2) have been successfully isolated in good yields. Compounds 1 and 2 are the first two examples of metal carbonyl derivatives of heteromolybdate with tellurium as the central atom. These two compounds have been thoroughly characterized by single-crystal X-ray diffraction, elemental analyses, X-ray powder diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, and UV-Vis spectroscopy. The electrochemical catalytic activities of 1 and 2 including cyclic voltammetry and catalytic oxidation of nitrite have also been investigated.

Graphical abstract: Organometallic functionalized non-classical polyoxometalates: synthesis, characterization and electrochemical properties

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Publication details

The article was received on 30 Apr 2018, accepted on 12 Jun 2018 and first published on 14 Jun 2018


Article type: Paper
DOI: 10.1039/C8DT01712C
Citation: Dalton Trans., 2018,47, 9317-9323
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    Organometallic functionalized non-classical polyoxometalates: synthesis, characterization and electrochemical properties

    P. Zhang, V. Singh, J. Jia, D. Zhang, P. Ma, J. Wang and J. Niu, Dalton Trans., 2018, 47, 9317
    DOI: 10.1039/C8DT01712C

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